晶場理論
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它以過渡金屬錯合物的電子層結構為出發點,可以很好地解釋錯合物的磁性、顏色、立體構型、熱力學性質和錯合物畸變等主要問題,但不能合理解釋配位基的光譜化學序列和 ... Forfasternavigation,thisIframeispreloadingtheWikiwandpagefor晶場理論. 晶場理論 Connectedto: {{::readMoreArticle.title}} 維基百科,自由的百科全書 {{bottomLinkPreText}} {{bottomLinkText}} ThispageisbasedonaWikipediaarticlewrittenby contributors(read/edit). Textisavailableunderthe CCBY-SA4.0license;additionaltermsmayapply. Images,videosandaudioareavailableundertheirrespectivelicenses. Coverphotoisavailableunder{{::mainImage.info.license.name||'Unknown'}}license. Coverphotoisavailableunder{{::mainImage.info.license.name||'Unknown'}}license. Credit: (seeoriginalfile). 晶場理論 Introduction 概述 能級分裂 分裂能 高自旋和低自旋 晶體場穩定化能 光學性質 對錯合物顏色的解釋 顏色理論 姜-泰勒效應 能級分裂圖 各種構型 參考資料 參見 {{current.index+1}}of{{items.length}} Date:{{current.info.dateOriginal||'Unknown'}} Date:{{(current.info.date|date:'mediumDate')||'Unknown'}} Credit: Uploadedby:{{current.info.uploadUser}}on{{current.info.uploadDate|date:'mediumDate'}} License:{{current.info.license.usageTerms||current.info.license.name||current.info.license.detected||'Unknown'}} License:{{current.info.license.usageTerms||current.info.license.name||current.info.license.detected||'Unknown'}} ViewfileonWikipedia Suggestascoverphoto Wouldyouliketosuggestthisphotoasthecoverphotoforthisarticle? Yes,thiswouldmakeagoodchoice No,nevermind Thankyouforhelping! Yourinputwillaffectcoverphotoselection,alongwithinputfromotherusers. Listentothisarticle Thanksforreportingthisvideo! {{result.lang}} {{result.T}} Nomatchingarticlesfound Searchforarticlescontaining:{{search.query}} ThisbrowserisnotsupportedbyWikiwand:(Wikiwandrequiresabrowserwithmoderncapabilitiesinordertoprovideyouwiththebestreadingexperience.Pleasedownloadanduseoneofthefollowingbrowsers: Chrome11+ Firefox4+ Safari6.1.2+ InternetExplorer10+ AnextensionyouusemaybepreventingWikiwandarticlesfromloadingproperly. Ifyou'reusingHTTPSEverywhereoryou'reunabletoaccessanyarticleonWikiwand,pleaseconsiderswitchingtoHTTPS(https://www.wikiwand.com). SwitchWikiwandtoHTTPS AnextensionyouusemaybepreventingWikiwandarticlesfromloadingproperly. IfyouareusinganAd-Blocker,itmighthavemistakenlyblockedourcontent. YouwillneedtotemporarilydisableyourAd-blockertoviewthispage. ✕ Thisarticlewasjustedited,clicktoreload ThisarticlehasbeendeletedonWikipedia(Why?) Backtohomepage PleaseclickAddinthedialogabove PleaseclickAllowinthetop-leftcorner,thenclickInstallNowinthedialog PleaseclickOpeninthedownloaddialog,thenclickInstall Pleaseclickthe"Downloads"iconintheSafaritoolbar,openthefirstdownloadinthelist,thenclickInstall {{::$root.activation.text}} InstallWikiwand InstallonChrome InstallonFirefox Don'tforgettorateus TellyourfriendsaboutWikiwand! Gmail Facebook Twitter Link EnjoyingWikiwand? Tellyourfriendsandspreadthelove: ShareonGmail ShareonFacebook ShareonTwitter ShareonBuffer {{::lang.langAbbreviation}} {{::lang.langEnglishName}}-{{::lang.langNativeName}} Yourpreferredlanguages {{::lang.NameEnglish}}-{{::lang.NameNative}} Alllanguages {{::lang.NameEnglish}}-{{::lang.NameNative}} FollowUs Don'tforgettorateus Ourmagicisn'tperfect Youcanhelpourautomaticcoverphotoselectionbyreportinganunsuitablephoto. Thisphotoisvisuallydisturbing Thisphotoisnotagoodchoice Thankyouforhelping! Yourinputwillaffectcoverphotoselection,alongwithinputfromotherusers. Ohno,there'sbeenanerror [email protected] Letusknowwhatyou'vedonethatcausedthiserror,whatbrowseryou'reusing,andwhetheryouhaveanyspecialextensions/add-onsinstalled. Thankyou!
延伸文章資訊
- 1晶場理論- 維基百科,自由的百科全書
由於不同的配位基導致的分裂能大不相同,因此錯合物的顏色也有很大差異。金屬原子不變時,弱場致使分裂能減小,光的波長增加,頻率減小;強場則使分裂能增 ...
- 2過渡金屬與配位化學
錯合物的顏色. 對大部分的錯合物而言,d軌域能量差亦恰巧落. 在可見光區,所以大部分錯合物都具有顏色,改. 變配位基就會改變Δo,使激發所需能量發生變.
- 3八面體錯合物(三)Octahedral Complexes(Ⅲ)
八面體錯合物(三)Octahedral Complexes(Ⅲ) ... 特定金屬離子的配位子,會決定金屬離子的分裂d軌域的能量差,因此當配位子改變時,顏色也會改變,會 ...
- 4晶場理論
它以過渡金屬錯合物的電子層結構為出發點,可以很好地解釋錯合物的磁性、顏色、立體構型、熱力學性質和錯合物畸變等主要問題,但不能合理解釋配位基的光譜化學序列和 ...
- 5錯合物- 維基百科,自由的百科全書
傳統配位化合物由一個以上的錯離子(也叫離子錯合物)形成,配位鍵中的 ... 可以較好地解釋配位數、幾何構型、磁性等一些性質,但對錯合物的顏色和光譜卻無能為力。